Piezoelectric energy harvesting device and method of fabricating the same

ABSTRACT

A flexible piezoelectric energy harvesting device includes a first flexible electrode substrate, a piezoelectric layer disposed on the first flexible electrode substrate, and a second flexible electrode substrate disposed on the piezoelectric layer. The piezoelectric layer may include a plurality of first piezoelectric lines spaced apart from each other in one direction and a plurality of second piezoelectric lines respectively filling spaces between the first piezoelectric lines.

CROSS-REFERENCE TO RELATED APPLICATIONS

This U.S. non-provisional patent application claims priority under 35U.S.C. §119 to Korean Patent Application No. 10-2012-0141161, filed onDec. 6, 2012, the entirety of which is incorporated by reference herein.

BACKGROUND

The inventive concept relates to piezoelectric energy harvesting devicesand methods of fabricating the same and, more particularly, to flexiblepiezoelectric energy harvesting devices using piezoelectric lines orpiezoelectric islands and methods of fabricating the same.

An energy harvesting technique converts wasted environmental energy intoelectrical energy to improve the energy efficiency of electronicproducts or electronic devices. Ultimately, the energy harvestingtechnique may enable stand-alone operation and/or self-charging of theelectronic products or devices by using the environmental energy withoutadditional supply of electrical energy.

If mechanical energy is applied to a piezoelectric material, thepiezoelectric material generates electrical energy. Thus, an energyharvesting technique using the piezoelectric material converts themechanical energy (e.g., force, pressure, and/or vibration) wasted inthe circumference into the electrical energy available to us.

The energy harvesting technique using the piezoelectric material may useenvironmental energy sources such as the vibration of motors/pumps,human movement, the flow of water, and/or a wind to generate theelectrical energy in a dark place without sunlight and/or at night.

However, a piezoelectric ceramic material used as piezoelectric materialmay have brittle and/or rigid properties. Thus, the piezoelectricceramic material may be difficult to be applied to a device having apredetermined shape. Additionally, the piezoelectric ceramic materialmay have poor durability under shock or impulse.

Generally, a piezoelectric energy harvesting (PEH) device may include apiezoelectric wafer and a non-piezoelectric layer. The piezoelectricwafer may generate the electrical energy by vibration, pressure, sound,and/or deformation. The non-piezoelectric layer may be provided tosupplement the brittle property of the piezoelectric material. Thenon-piezoelectric layer may include silicon, aluminum, copper, and/or aprinted circuit board (PCB), etc. However, the combined structure of thepiezoelectric material and the non-piezoelectric layer may havehardness, such that it may not be easily applied to application fields(e.g., the human body and/or clothes) requiring flexible properties.

A piezoelectric polymer has been suggested for resolving the aboveproblems. However, the piezoelectric characteristics of thepiezoelectric polymer may be very lower than that of the piezoelectricceramic. Thus, the piezoelectric polymer may generate a low power of afew micro watt levels.

SUMMARY

Embodiments of the inventive concept may provide flexible piezoelectricenergy harvesting devices capable of improving stability and the amountof generated electrical energy.

Embodiments of the inventive concept may provide methods of fabricatinga flexible piezoelectric energy harvesting device capable of improvingstability and the amount of generated electrical energy.

In one aspect, a flexible piezoelectric energy harvesting device mayinclude: a first flexible electrode substrate; a piezoelectric layerdisposed on the first flexible electrode substrate, the piezoelectriclayer including a plurality of first piezoelectric lines spaced apartfrom each other in one direction and a plurality of second piezoelectriclines respectively filling spaces between the first piezoelectric lines;and a second flexible electrode substrate disposed on the piezoelectriclayer.

In an embodiment, the first and second flexible electrode substrates mayinclude a conductive material.

In an embodiment, each of the first and second flexible electrodesubstrates may include: an insulating polymer layer; and an electrodepattern disposed on a surface of the insulating polymer layer which isadjacent to the piezoelectric layer.

In an embodiment, the electrode pattern may have an interdigitatedelectrode (IDE) structure.

In an embodiment, the first piezoelectric lines may include apiezoelectric ceramic material or a single-crystalline material.

In an embodiment, the first piezoelectric lines may include thepiezoelectric ceramic material; and the piezoelectric ceramic materialmay include lead zirconate titanate (PZT) or lead-free ceramicmaterials.

In an embodiment, the first piezoelectric lines may include thesingle-crystalline material; and the single-crystalline material mayinclude lead magnesium niobate-lead titanate (PMN-PT), lead magnesiumniobate-lead zirconate titanate (PMN-PZT), lead indium niobate-leadtitanate (PIN-PT), or lead zirconate niobate-lead titanate (PZN-PT).

In an embodiment, the second piezoelectric lines may include apiezoelectric polymer material; and the piezoelectric polymer materialmay include a polyvinylidene difluoride (PVDF) polymer-basedpiezoelectric material, or a polyvinylidene difluoride-trifluoroethylene(PVDF-TrFE) polymer-based piezoelectric material.

In an embodiment, each of the first and second piezoelectric lines mayhave a quadrilateral cross section in another direction crossing the onedirection.

In another aspect, a flexible piezoelectric energy harvesting device mayinclude: a first flexible electrode substrate; a piezoelectric layerdisposed on the first flexible electrode substrate, the piezoelectriclayer including a plurality of piezoelectric islands spaced apart fromeach other and regularly arranged and a piezoelectric net patternfilling spaces between the piezoelectric islands; and a second flexibleelectrode substrate disposed on the piezoelectric layer.

In still another aspect, a method of fabricating a flexiblepiezoelectric energy harvesting device may include: forming apiezoelectric layer on a first flexible electrode substrate, thepiezoelectric layer including a plurality of first piezoelectric linesspaced apart from each other in one direction and a plurality of secondpiezoelectric lines respectively filling spaces between the firstpiezoelectric lines; and forming a second flexible electrode substrateon the piezoelectric layer.

In an embodiment, the first and second flexible electrode substrates mayinclude a conductive material.

In an embodiment, each of the first and second flexible electrodesubstrates may include: an insulating polymer layer; and an electrodepattern disposed on a surface of the insulating polymer layer which isadjacent to the piezoelectric layer. The electrode pattern may have aninterdigitated electrode (IDE) structure.

In an embodiment, forming the piezoelectric layer may include: forming afirst piezoelectric layer on a sacrificial substrate; patterning thefirst piezoelectric layer to form the first piezoelectric lines spacedapart from each other in the one direction; forming the secondpiezoelectric lines filling the spaces between the first piezoelectriclines, respectively; and moving the piezoelectric layer including thefirst and second piezoelectric lines disposed on the sacrificialsubstrate onto the first flexible electrode substrate.

In an embodiment, the first piezoelectric layer may be formed of apiezoelectric ceramic material or a single-crystalline material.

In an embodiment, the piezoelectric ceramic material may include leadzirconate titanate (PZT) or lead-free ceramic materials.

In an embodiment, the single-crystalline material may include leadmagnesium niobate-lead titanate (PMN-PT), lead magnesium niobate-leadzirconate titanate (PMN-PZT), lead indium niobate-lead titanate(PIN-PT), or lead zirconate niobate-lead titanate (PZN-PT).

In an embodiment, each of the first piezoelectric lines may be formed tohave a quadrilateral cross section in another direction crossing the onedirection.

In an embodiment, the second piezoelectric lines may be formed of apiezoelectric polymer material; and the piezoelectric polymer materialmay include a polyvinylidene difluoride (PVDF) polymer-basedpiezoelectric material, or a polyvinylidene difluoride-trifluoroethylene(PVDF-TrFE) polymer-based piezoelectric material.

BRIEF DESCRIPTION OF THE DRAWINGS

The inventive concept will become more apparent in view of the attacheddrawings and accompanying detailed description.

FIG. 1 is a perspective view illustrating a flexible piezoelectricenergy harvesting device according to some embodiments of the inventiveconcept;

FIGS. 2A to 2F are perspective views illustrating a method offabricating a flexible piezoelectric energy harvesting device accordingto embodiments of the inventive concept; and

FIGS. 3 and 4 are perspective views illustrating flexible piezoelectricenergy harvesting devices according to other embodiments of theinventive concept.

DETAILED DESCRIPTION OF THE EMBODIMENTS

The inventive concept will now be described more fully hereinafter withreference to the accompanying drawings, in which exemplary embodimentsof the inventive concept are shown. The advantages and features of theinventive concept and methods of achieving them will be apparent fromthe following exemplary embodiments that will be described in moredetail with reference to the accompanying drawings. It should be noted,however, that the inventive concept is not limited to the followingexemplary embodiments, and may be implemented in various forms.Accordingly, the exemplary embodiments are provided only to disclose theinventive concept and let those skilled in the art know the category ofthe inventive concept. In the drawings, embodiments of the inventiveconcept are not limited to the specific examples provided herein and areexaggerated for clarity.

The terminology used herein is for the purpose of describing particularembodiments only and is not intended to limit the invention. As usedherein, the singular terms “a,” “an” and “the” are intended to includethe plural forms as well, unless the context clearly indicatesotherwise. As used herein, the term “and/or” includes any and allcombinations of one or more of the associated listed items. It will beunderstood that when an element is referred to as being “connected” or“coupled” to another element, it may be directly connected or coupled tothe other element or intervening elements may be present.

Similarly, it will be understood that when an element such as a layer,region or substrate is referred to as being “on” another element, it canbe directly on the other element or intervening elements may be present.In contrast, the term “directly” means that there are no interveningelements. It will be further understood that the terms “comprises”,“comprising,”, “includes” and/or “including”, when used herein, specifythe presence of stated features, integers, steps, operations, elements,and/or components, but do not preclude the presence or addition of oneor more other features, integers, steps, operations, elements,components, and/or groups thereof.

Additionally, the embodiment in the detailed description will bedescribed with sectional views as ideal exemplary views of the inventiveconcept. Accordingly, shapes of the exemplary views may be modifiedaccording to manufacturing techniques and/or allowable errors.Therefore, the embodiments of the inventive concept are not limited tothe specific shape illustrated in the exemplary views, but may includeother shapes that may be created according to manufacturing processes.Areas exemplified in the drawings have general properties, and are usedto illustrate specific shapes of elements. Thus, this should not beconstrued as limited to the scope of the inventive concept.

It will be also understood that although the terms first, second, thirdetc. may be used herein to describe various elements, these elementsshould not be limited by these terms. These terms are only used todistinguish one element from another element. Thus, a first element insome embodiments could be termed a second element in other embodimentswithout departing from the teachings of the present invention. Exemplaryembodiments of aspects of the present inventive concept explained andillustrated herein include their complementary counterparts. The samereference numerals or the same reference designators denote the sameelements throughout the specification.

Moreover, exemplary embodiments are described herein with reference tocross-sectional illustrations and/or plane illustrations that areidealized exemplary illustrations. Accordingly, variations from theshapes of the illustrations as a result, for example, of manufacturingtechniques and/or tolerances, are to be expected. Thus, exemplaryembodiments should not be construed as limited to the shapes of regionsillustrated herein but are to include deviations in shapes that result,for example, from manufacturing. For example, an etching regionillustrated as a rectangle will, typically, have rounded or curvedfeatures. Thus, the regions illustrated in the figures are schematic innature and their shapes are not intended to illustrate the actual shapeof a region of a device and are not intended to limit the scope ofexample embodiments.

To solve conventional problems, piezoelectric fiber composites (PFCs)have been developed. The piezoelectric fiber composites includes anactive-fiber composite (AFC) and a macro-fiber composite (MFC).

The active-fiber composite includes a piezoelectric ceramic fiber whichis roundly extruded; and a resin (e.g., an epoxy) surrounding thepiezoelectric ceramic fiber. The resin of the active-fiber compositeprevents the piezoelectric ceramic fiber from being broken and providesflexibility to the piezoelectric ceramic fiber.

An electrode of a flexible piezoelectric energy harvesting device has ainterdigitated electrode (IDE) shape. The interdigitated electrode maygenerate an electric field substantially parallel to a fiberpolarization direction of the piezoelectric fiber composite or may causemodification. The piezoelectric device including the electrode of theinterdigitated electrode shape uses a strong piezoelectric chargecoefficient (d₃₃) of the piezoelectric ceramic, so as to be used as anactuator or an oscillation attenuator of an apparatus.

However, due to the active-fiber composite of the round shape, suitablebonding of the interdigitated electrode may not be easy and a contactarea may be small. Thus, if the active-fiber composite is in theactuator, the actuator may require a voltage greater than a voltagecalculated for obtaining a variation amount of the actuator.Additionally, a fabricating process of the active-fiber composite may bedifficult, and reproducibility of the active-fiber composite may bereduced. Furthermore, a fabrication cost of the active-fiber compositemay increase.

For solving the problems of the active-fiber composite, the macro-fibercomposites have been developed in National aeronautics and spaceadministration (NASA). Similarly to the active-fiber composite, themacro-fiber composite includes piezoelectric ceramic fibers, a resininjected therebetween, and two electrode arrays of the interdigitatedelectrode shape. The piezoelectric ceramic fibers and the resin aredisposed between the two electrode arrays.

However, unlike the active-fiber composite having the piezoelectricfiber of the round shape, the piezoelectric fiber of the macro-fibercomposite has a quadrilateral cross section, and a uniform space existsbetween the piezoelectric fibers of the macro-fiber composite. Thepiezoelectric fibers are accurately arranged in parallel to each otherin a macro-fiber composite package.

A fabricating process of the macro-fiber composite is simpler than thatof the active-fiber composite. Thus, a fabricating cost of themacro-fiber composite is reduced. The piezoelectric fiber having thequadrilateral cross section may use a raw material formed in afabricating process of the piezoelectric ceramic. In other words, thepiezoelectric ceramic may be divided into small sized piezoelectricfibers by a repeated and cheap fabricating process (e.g., a cuttingprocess using a dicing saw or laser). Thus, mass-production of thepiezoelectric fibers may be realized and the piezoelectric fibers may beeffectively produced in costs.

Additionally, the piezoelectric fibers of the macro-fiber composite havethe quadrilateral cross sections, such that they may become easily incontact with the interdigitated electrode. Moreover, an electric fieldgenerated from the interdigitated electrode may decrease by the resinhaving a low dielectric constant. The piezoelectric charge coefficientof the macro-fiber composite may be improved to about 150% of thepiezoelectric charge coefficient of the active-fiber composite for theimproved electrical contact ob the piezoelectric fiber and theinterdigitated electrode.

However, since the piezoelectric fiber composites such as theactive-fiber composite and the macro-fiber composite use the resinbetween the piezoelectric fibers, while the flexibility of thepiezoelectric fiber composites increases, electrical output of thepiezoelectric fiber composites may be reduced. Additionally, since thepiezoelectric fiber composites are fabricated under vacuum, theirfabricating costs may increase. For resolving the problems, embodimentsof the inventive concept will provide the following flexiblepiezoelectric energy harvesting devices and methods of fabricating thesame.

FIG. 1 is a perspective view illustrating a flexible piezoelectricenergy harvesting device according to some embodiments of the inventiveconcept.

Referring to FIG. 1, a flexible piezoelectric energy harvesting devicemay include a lower flexible electrode substrate 51, a piezoelectriclayer disposed on the lower flexible electrode substrate 51, and anupper flexible electrode substrate 50 disposed on the piezoelectriclayer. The piezoelectric layer may consist of a plurality of firstpiezoelectric lines 11 spaced apart from each other in one direction anda plurality of second piezoelectric lines 30 respectively filling spacesbetween the first piezoelectric lines 11. In other words, the firstpiezoelectric lines 11 and the second piezoelectric lines 30 may bealternately and repeatedly arranged in the one direction.

The upper and lower flexible electrode substrates 50 and 51 may includea conductive material such as aluminum (Al), copper (Cu), silver (Ag),and/or gold (Au). In other words, each of the upper and lower flexibleelectrode substrates 50 and 51 may be a flexible metal substrate. Thatis, the metal substrate may have a thickness capable of providing theflexibility to the metal substrate. Alternatively, each of the upper andlower flexible electrode substrates 50 and 51 may consist of aninsulating polymer layer and a metal sheet disposed on one surface ofthe insulating polymer layer.

The metal sheet may have a thickness capable of providing theflexibility to the metal sheet. An epoxy or a conductive film havingadhesive property may be disposed between the metal sheet and the onesurface of the insulating polymer layer. In other words, the metal sheetmay be bonded to the one surface of the insulating polymer layer by theepoxy or conductive film. In still another embodiment, each of the upperand lower flexible electrode substrates 50 and 51 may consist of theinsulating polymer layer and an electrode layer formed on the insulatingpolymer layer by a screen printing method using a silver paste. In thiscase, the electrode layer has a thickness capable of providing theflexibility to the electrode layer.

The upper and lower flexible electrode substrates 50 and 51 may be indirect contact with the piezoelectric layer. In other words, the upperand lower flexible electrode substrates 50 and 51 may be in directcontact with the first and second piezoelectric lines 11 and 30. Here,each of the first and second piezoelectric lines 11 and 30 may have aquadrilateral cross section in an extending direction of each of thefirst and second piezoelectric lines 11 and 30. Thus, electrical contactbetween the piezoelectric layer and the upper and lower flexibleelectrode substrates 50 and 51 may be improved to increase thepiezoelectric charge coefficient of the flexible piezoelectric energyharvesting device.

The first piezoelectric lines 11 may include a piezoelectric ceramicmaterial or a single-crystalline material. The piezoelectric ceramicmaterial may include lead zirconate titanate (PZT) or lead-free ceramicmaterials. The single-crystalline material may include lead magnesiumniobate-lead titanate (PMN-PT), lead magnesium niobate-lead zirconatetitanate (PMN-PZT), lead indium niobate-lead titanate (PIN-PT), or leadzirconate niobate-lead titanate (PZN-PT).

The second piezoelectric lines 30 may include a piezoelectric polymermaterial. The piezoelectric polymer material may include apolyvinylidene difluoride (PVDF) polymer-based piezoelectric material,or a polyvinylidene difluoride-trifluoroethylene (PVDF-TrFE)polymer-based piezoelectric material.

As a result, the flexible piezoelectric energy harvesting deviceincludes the piezoelectric layer consisting of the first and secondpiezoelectric lines 11 and 30 having the quadrilateral cross sections inthe extending direction of the first and second piezoelectric lines 11and 30. Thus, the flexible piezoelectric energy harvesting device mayhave high flexibility and the improved piezoelectric charge coefficient.As a result, it is possible to greatly improve the amount of electricalenergy obtained by the flexible piezoelectric energy harvesting device.

FIGS. 2A to 2F are perspective views illustrating a method offabricating a flexible piezoelectric energy harvesting device accordingto embodiments of the inventive concept.

Referring to FIG. 2A, a first piezoelectric layer 10 is formed on asacrificial substrate 20. The sacrificial substrate 20 may include anon-conductive material. The non-conductive material may be a polymer.For example, the sacrificial substrate 20 may include poly(ethyleneterephthalate), poly(butylenes terephthalate), polyimide, polyester,and/or poly olefine (polyethylene, polypropylene). In other words,polymer film may be used as the sacrificial substrate 20. Additionally,the sacrificial substrate 20 may have a little adhesive property.Alternatively, an adhesive layer (not shown) may be disposed between thesacrificial substrate 20 and the first piezoelectric layer 10.

The first piezoelectric layer 10 may include a piezoelectric ceramicmaterial or a single-crystalline material. The piezoelectric ceramicmaterial may include lead zirconate titanate (PZT) or lead-free ceramicmaterials. The single-crystalline material may include lead magnesiumniobate-lead titanate (PMN-PT), lead magnesium niobate-lead zirconatetitanate (PMN-PZT), lead indium niobate-lead titanate (PIN-PT), or leadzirconate niobate-lead titanate (PZN-PT).

Referring to FIG. 2B, the first piezoelectric layer 10 is patterned toform first piezoelectric lines 11 extending in a first direction andslits 12 between the first piezoelectric lines 11. The firstpiezoelectric layer 10 may be patterned by a cutting process using anaccurately controlled dicing saw or laser. During the cutting process,the sacrificial substrate 20 is not cut but the first piezoelectriclayer 10 is completely cut to form the first piezoelectric lines 11separated from each other. Thus, each of the first piezoelectric lines11 may have a quadrilateral cross section in the extending direction ofthe first piezoelectric 11. Additionally, lengths of the firstpiezoelectric lines 11 may be substantially equal to each other andwidths of the first piezoelectric lines 11 may be substantially equal toeach other. Each of the slits 12 between the first piezoelectric lines11 may have a minimum width realized by the cutting process.

Referring to FIGS. 2C and 2D, second piezoelectric lines 30 are formedto fill the slits 12, respectively. The slits 12 correspond to spacesbetween the first piezoelectric lines 11 spaced apart from each other ina second direction crossing the extending direction (i.e., the firstdirection) of the first piezoelectric lines 11. As a result, apiezoelectric layer may be formed to consist of the first piezoelectriclines 11 and the second piezoelectric lines 30 filling the slits 12corresponding to the spaces between the first piezoelectric lines 11.

The second piezoelectric lines 30 may be formed of a piezoelectricpolymer material. The piezoelectric polymer material may include apolyvinylidene difluoride (PVDF) polymer-based piezoelectric material,or a polyvinylidene difluoride-trifluoroethylene (PVDF-TrFE)polymer-based piezoelectric material.

Forming the second piezoelectric lines 30 may include filling the slits12 with a liquid piezoelectric polymer material 30 exhausted through aneedle of a taylor cone 31 containing the liquid piezoelectric polymermaterial 30. At this time, the sacrificial substrate 20 and the taylorcone 31 may be accurately moved along moving directions 32 and 33 by amotion controller, respectively. The liquid piezoelectric polymermaterial 30 exhausted through the needle of the taylor cone 31 may fillthe slits 12 by the movement of the taylor cone 31 and the sacrificialsubstrate 20. At this time, the liquid piezoelectric polymer material 30may be stretched to fill the slits 12. In other words, a diameter of theneedle of the taylor cone 31 may be determined depending on the width ofthe slits 12, such that the liquid piezoelectric polymer material 30 maycompletely fill the slits 12 between the first piezoelectric lines 11spaced apart from the second direction.

Since the first piezoelectric lines 11 have the quadrilateral crosssection in the extending direction of the first piezoelectric line 11,the second piezoelectric lines 30 filling the slits 12 (i.e., thespaces) between the first piezoelectric lines 11 may also havequadrilateral cross sections in the extending direction. Thus,electrical contact of the piezoelectric layer and flexible electrodesubstrates 50 and 51 of FIG. 2F may be improved.

Referring to FIGS. 2E and 2F, the piezoelectric layer on the sacrificialsubstrate 20 is moved on a prepared lower flexible electrode substrate51. An upper flexible electrode substrate 50 is formed on thepiezoelectric layer disposed on the lower flexible electrode substrate51.

The upper and lower flexible electrode substrates 50 and 51 may includea conductive material such as aluminum (Al), copper (Cu), silver (Ag),and/or gold (Au). In other words, each of the upper and lower flexibleelectrode substrates 50 and 51 may be a flexible metal substrate.Alternatively, each of the upper and lower flexible electrode substrates50 and 51 may consist of an insulating polymer layer and a flexiblemetal sheet disposed on one surface of the insulating polymer layer. Anepoxy or a conductive film having adhesive property may be disposedbetween the metal sheet and the one surface of the insulating polymerlayer. In other words, the metal sheet may be bonded to the one surfaceof the insulating polymer layer by the epoxy or conductive film havingthe adhesive property. In still another embodiment, each of the upperand lower flexible electrode substrates 50 and 51 may consist of theinsulating polymer layer, and an electrode layer formed on theinsulating polymer layer by a screen printing method using a silverpaste. In this case, the electrode layer has a thickness capable ofproviding the flexibility to the electrode layer.

The upper and lower flexible electrode substrates 50 and 51 may be indirect contact with the piezoelectric layer. In other words, the upperand lower flexible electrode substrates 50 and 51 may be in directcontact with the first and second piezoelectric lines 11 and 30. Here,each of the first and second piezoelectric lines 11 and 30 may have thequadrilateral cross section in the extending direction of the first andsecond piezoelectric lines 11 and 30. Thus, electrical contact betweenthe piezoelectric layer and the upper and lower flexible electrodesubstrates 50 and 51 may be improved to increase the piezoelectriccharge coefficient of the flexible piezoelectric energy harvestingdevice.

A predetermined voltage may be applied to the upper and lower flexibleelectrode substrates 50 and 51, such that polarization may generate inthe upper and lower flexible electrode substrates 50 and 51. Thus, theflexible piezoelectric energy harvesting device may be fabricated.

As a result, the flexible piezoelectric energy harvesting devicefabricated by the aforementioned method includes the piezoelectric layerconsisting of the first and second piezoelectric lines 11 and 30 havingthe quadrilateral cross section in the extending direction of the firstand second piezoelectric lines 11 and 30. Thus, the flexiblepiezoelectric energy harvesting device may have high flexibility and theimproved piezoelectric charge coefficient. As a result, it is possibleto provide the method of fabricating the flexible piezoelectric energyharvesting device capable of greatly improving the amount of obtainedelectrical energy.

Hereinafter, flexible piezoelectric energy harvesting devices accordingto other embodiments will be described with reference to FIGS. 3 and 4.FIGS. 3 and 4 are perspective views illustrating flexible piezoelectricenergy harvesting devices according to other embodiments of theinventive concept. In the present embodiments, the same elements asdescribed in the above embodiments will be indicated by the samereference numerals and the same reference designators. The descriptionsto the same elements as in the aforementioned embodiments will beomitted or mentioned briefly.

A flexible piezoelectric energy harvesting device in FIG. 3 may includelower and upper flexible electrode substrates having differentstructures from those of the flexible electrode substrates 51 and 50 ofthe flexible piezoelectric energy harvesting device according to theaforementioned embodiment.

Referring to FIG. 3, each of the lower and upper flexible electrodesubstrates may include an insulating polymer layer 52 a or 52 b and anelectrode pattern disposed on one surface of the insulating polymerlayer 52 a or 52 b which is adjacent to the piezoelectric layer. Theinsulating polymer layer 52 a or 52 b may include polyimide. Theelectrode pattern may have an interdigitated electrode (IDE) structure.The IDE structure may consist of body portions 60 a or 60 b opposite toeach other and tooth portions 61 a or 61 b extending from the bodyportions 60 a or 60 b and being alternately arranged.

The flexible piezoelectric energy harvesting device including theelectrode patterns of the IDE structures uses a great piezoelectriccharge coefficient (d₃₃) of the first piezoelectric lines 11 of thepiezoelectric layer, such that the amount of the generated electricalenergy may be improved.

A metal sheet having a thickness capable of providing the flexibilitythereto may be formed on a surface of the insulating polymer layer 52 aor 52 b, and then the metal sheet may be patterned using aphotolithography process to form the electrode pattern having the IDEstructure. The electrode pattern having the IDE structure may be formedto have the thickness capable of providing the flexibility to theelectrode pattern by performing an electron-beam deposition process onthe surface of the insulating polymer layer 52 a or 52 b. In anotherembodiment, the electrode pattern having the IDE structure may beseparately formed to have the thickness capable of providing theflexibility to the electrode pattern and then may be bonded to thesurface of the insulating polymer layer 52 a or 52 b. In this case, anepoxy or a conductive film having an adhesive property may be formedbetween the electrode pattern and the surface of the insulating polymerlayer 52 a or 52 b. In still another embodiment, the electrode patternhaving the IDE structure may be formed to have the thickness capable ofproviding the flexibility to the electrode pattern by performing ascreen printing method using a silver paste on the surface of theinsulating polymer layer 52 a or 52 b.

A flexible piezoelectric energy harvesting device in FIG. 4 has apiezoelectric layer of a different structure from the piezoelectriclayer of the flexible piezoelectric energy harvesting devices accordingto the embodiments described above.

Referring to FIG. 4, a piezoelectric layer may include firstpiezoelectric islands 11 i spaced apart from each other and regularlyarranged, and a second piezoelectric net pattern 30 n filling spacesbetween the first piezoelectric islands 11 i.

Each of the first piezoelectric islands 11 i may have quadrilateralcross section in one direction, and the second piezoelectric net pattern30 n may fill the spaces between the first piezoelectric islands 11 i.Thus, the electrical contact between the piezoelectric layer and theupper and low flexible electrode substrates 50 and 51 may be improved toimprove the piezoelectric charge coefficient of the flexiblepiezoelectric energy harvesting device.

The first piezoelectric islands 11 i may include a piezoelectric ceramicmaterial or a single-crystalline material. The piezoelectric ceramicmaterial may include lead zirconate titanate (PZT) or lead-free ceramicmaterials. The single-crystalline material may include lead magnesiumniobate-lead titanate (PMN-PT), lead magnesium niobate-lead zirconatetitanate (PMN-PZT), lead indium niobate-lead titanate (PIN-PT), or leadzirconate niobate-lead titanate (PZN-PT).

The second piezoelectric net pattern 30 n may include a piezoelectricpolymer material. The piezoelectric polymer material may include apolyvinylidene difluoride (PVDF) polymer-based piezoelectric material,or a polyvinylidene difluoride-trifluoroethylene (PVDF-TrFE)polymer-based piezoelectric material.

After the first piezoelectric lines 11 of FIG. 2B are formed, the firstpiezoelectric lines 11 may be additionally patterned in a directioncrossing the extending direction of the first piezoelectric lines 11 toform the first piezoelectric islands 11 i.

Similarly to the process of filling the slits 12 of FIG. 2C, the liquidpiezoelectric polymer material 30 of FIG. 2C may fill the spaces betweenthe first piezoelectric islands 11 i to form the second piezoelectricnet pattern 30 n.

As described above, the flexible piezoelectric energy harvesting devicesaccording to embodiments include the piezoelectric layer consisting ofthe first piezoelectric lines or islands of the piezoelectric ceramicmaterial or the single-crystalline material and the second piezoelectriclines or net pattern of the piezoelectric polymer material. Thus, theflexible piezoelectric energy harvesting devices may have theflexibility but may not be easily broken. As a result, the flexiblepiezoelectric energy harvesting devices may be easily applied to objectshaving predetermined shapes such as the human body and/or clothes, andthe amount of the electrical energy obtained by the flexiblepiezoelectric energy harvesting devices may be improved. The flexiblepiezoelectric energy harvesting devices may be used along with aflexible solar energy harvesting device, a flexible thermoelectricenergy harvesting device, and/or a flexible battery. Thus, the flexiblepiezoelectric energy harvesting devices may be applied to variousmulti-energy sources.

While the inventive concept has been described with reference to exampleembodiments, it will be apparent to those skilled in the art thatvarious changes and modifications may be made without departing from thespirit and scope of the inventive concept. Therefore, it should beunderstood that the above embodiments are not limiting, butillustrative. Thus, the scope of the inventive concept is to bedetermined by the broadest permissible interpretation of the followingclaims and their equivalents, and shall not be restricted or limited bythe foregoing description.

What is claimed is:
 1. A flexible piezoelectric energy harvesting devicecomprising: a first flexible electrode substrate; a piezoelectric layerdisposed on the first flexible electrode substrate, the piezoelectriclayer including a plurality of first piezoelectric lines spaced apartfrom each other in one direction and a plurality of second piezoelectriclines respectively filling spaces between the first piezoelectric lines;and a second flexible electrode substrate disposed on the piezoelectriclayer.
 2. The flexible piezoelectric energy harvesting device of claim1, wherein the first and second flexible electrode substrates include aconductive material.
 3. The flexible piezoelectric energy harvestingdevice of claim 1, wherein each of the first and second flexibleelectrode substrates comprises: an insulating polymer layer; and anelectrode pattern disposed on a surface of the insulating polymer layerwhich is adjacent to the piezoelectric layer.
 4. The flexiblepiezoelectric energy harvesting device of claim 3, wherein the electrodepattern has an interdigitated electrode (IDE) structure.
 5. The flexiblepiezoelectric energy harvesting device of claim 1, wherein the firstpiezoelectric lines include a piezoelectric ceramic material or asingle-crystalline material.
 6. The flexible piezoelectric energyharvesting device of claim 5, wherein the first piezoelectric linesinclude the piezoelectric ceramic material; and wherein thepiezoelectric ceramic material includes lead zirconate titanate (PZT) orlead-free ceramic materials.
 7. The flexible piezoelectric energyharvesting device of claim 5, wherein the first piezoelectric linesinclude the single-crystalline material; and wherein thesingle-crystalline material includes lead magnesium niobate-leadtitanate (PMN-PT), lead magnesium niobate-lead zirconate titanate(PMN-PZT), lead indium niobate-lead titanate (PIN-PT), or lead zirconateniobate-lead titanate (PZN-PT).
 8. The flexible piezoelectric energyharvesting device of claim 1, wherein the second piezoelectric linesinclude a piezoelectric polymer material; and wherein the piezoelectricpolymer material includes a polyvinylidene difluoride (PVDF)polymer-based piezoelectric material, or a polyvinylidenedifluoride-trifluoroethylene (PVDF-TrFE) polymer-based piezoelectricmaterial.
 9. The flexible piezoelectric energy harvesting device ofclaim 1, wherein each of the first and second piezoelectric lines has aquadrilateral cross section in another direction crossing the onedirection.
 10. A method of fabricating a flexible piezoelectric energyharvesting device, the method comprising: forming a piezoelectric layeron a first flexible electrode substrate, the piezoelectric layerincluding a plurality of first piezoelectric lines spaced apart fromeach other in one direction and a plurality of second piezoelectriclines respectively filling spaces between the first piezoelectric lines;and forming a second flexible electrode substrate on the piezoelectriclayer.
 11. The method of claim 10, wherein the first and second flexibleelectrode substrates include a conductive material.
 12. The method ofclaim 10, wherein each of the first and second flexible electrodesubstrates comprises: an insulating polymer layer; and an electrodepattern disposed on a surface of the insulating polymer layer which isadjacent to the piezoelectric layer.
 13. The method of claim 12, whereinthe electrode pattern has an interdigitated electrode (IDE) structure.14. The method of claim 10, wherein forming the piezoelectric layercomprises: forming a first piezoelectric layer on a sacrificialsubstrate; patterning the first piezoelectric layer to form the firstpiezoelectric lines spaced apart from each other in the one direction;forming the second piezoelectric lines filling the spaces between thefirst piezoelectric lines, respectively; and moving the piezoelectriclayer including the first and second piezoelectric lines disposed on thesacrificial substrate onto the first flexible electrode substrate. 15.The method of claim 14, wherein the first piezoelectric layer is formedof a piezoelectric ceramic material or a single-crystalline material.16. The method of claim 15, wherein the piezoelectric ceramic materialincludes lead zirconate titanate (PZT) or lead-free ceramic materials.17. The method of claim 15, wherein the single-crystalline materialincludes lead magnesium niobate-lead titanate (PMN-PT), lead magnesiumniobate-lead zirconate titanate (PMN-PZT), lead indium niobate-leadtitanate (PIN-PT), or lead zirconate niobate-lead titanate (PZN-PT). 18.The method of claim 14, wherein each of the first piezoelectric lines isformed to have a quadrilateral cross section in another directioncrossing the one direction.
 19. The method of claim 14, wherein thesecond piezoelectric lines are formed of a piezoelectric polymermaterial; and wherein the piezoelectric polymer material includes apolyvinylidene difluoride (PVDF) polymer-based piezoelectric material,or a polyvinylidene difluoride-trifluoroethylene (PVDF-TrFE)polymer-based piezoelectric material.
 20. A flexible piezoelectricenergy harvesting device comprising: a first flexible electrodesubstrate; a piezoelectric layer disposed on the first flexibleelectrode substrate, the piezoelectric layer including a plurality ofpiezoelectric islands spaced apart from each other and regularlyarranged and a piezoelectric net pattern filling spaces between thepiezoelectric islands; and a second flexible electrode substratedisposed on the piezoelectric layer.